Recent Publications


2016

Hideyuki Konishi, Fumika Hoshino, Kei Manabe “Practical Synthesis of Axially Chiral Dicarboxylates via Pd-Catalyzed External-CO-Free Carbonylation” Chem. Pharm. Bull. 2016, 64, 1438-1441.
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Miyuki Yamaguchi, Tomoyo Akiyama, Hirohisa Sasou, Haruka Katsumata, Kei Manabe “One-Pot Synthesis of Substituted Benzo[b]furans and Indoles from Dichlorophenols/Dichloroanilines Using a Palladium-Dihydroxyterphenylphosphine Catalyst”
J. Org. Chem. DOI: 10.1021/acs.joc.6b00824.
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Miyuki Yamaguchi, Mayu Higuchi, Kanae Tazawa, Kei Manabe “Three-Step Synthesis of Fluoranthenes through Pd-Catalyzed Inter and Intramolecular C−H Arylation”
J. Org. Chem. 2016, 81, 3967-3974.
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Miyuki Yamaguchi, Kei Manabe, “Ligand-Controlled Site-Selective Cross-Coupling” In Site-Selective Catalysis, Kawabata, T. Ed.:
Springer International Publishing: Switzerland, 2016, pp. 1-25.



2015

Yasutada Akiba, Takuya Inoue, Izumi Kaji, Masaaki Higashiyama, Kazuyuki Narimatsu, Ken-ichi Iwamoto, Masahiko Watanabe, Paul H. Guth, Eli Engel, Atsukazu Kuwahara, J. D. Kaunitz, “Short-chain fatty acid sensing in rat duodenumJournal of Physiology 2015, 593, 585-599.
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Miyuki Yamaguchi, Kohei Suzuki, Kei Manabe, “Scalable Synthesis of Dihydroxyterphenylphosphine Ligands” Tetrahedron 2015, 71, 2743-2747.
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Hideyuki Konishi, Takashi Muto, Tsuyoshi Ueda, Yayoi Yamada, Miyuki Yamaguchi, Kei Manabe, “Imidazole Derivatives as Accelerators for Ruthenium-Catalyzed Hydroesterification and Hydrocarbamoylation of Alkenes: Extensive Ligand Screening and Mechanistic Study” ChemCatChem 2015, 7, 836-845.

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Hideyuki Konishi, Hiroki Nagase, Kei Manabe, "Concise Synthesis of Cyclic Carbonyl Compounds from Haloarenes Using Phenyl Formate as the Carbonyl Source" Chem. Commun. 2015, 51, 1854-1857.

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2014

Kei Manabe, Miyuki Yamaguchi, "Catalyst-Controlled Site-Selectivity Switching in Pd-Catalyzed Cross-Coupling of Dihaloarenes" Catalysts 2014, 4, 307-320.
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Hideyuki Konishi, Kei Manabe, “Formic Acid Derivatives as Practical Carbon Monoxide Surrogates for Metal-Catalyzed Carbonylation Reactions” Synlett 2014, 25, 1971-1986.
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Miyuki Yamaguchi, Kei Manabe, “One-pot Synthesis of 2,4-Disubstituted Indoles from N-Tosyl-2,3-dichloroaniline Using Palladium-Dihydroxyterphenylphosphine Catalyst” Org. Lett. 2014, 16, 2386-2389.

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Hideyuki Konishi, Tsuyoshi Ueda, Kei Manabe, “Pd-Catalyzed External-CO-Free Carbonylation: Preparation of 2,4,6-Trichlorophenyl 3,4-Dihydronaphthalene-2-Carboxylate”
Org. Synth. 2014, 91, 39-51.




2013

Miyuki Yamaguchi, Takeshi Kimura, Naomi Shinohara, Kei Manabe, “Repetitive Two-Step Method for o,o,p- and o,p-Oligophenylene Synthesis through Pd-Catalyzed Cross-Coupling of Hydroxyterphenylboronic Acid” Molecules 2013, 18, 15207-15219.



Tsuyoshi Ueda, Hideyuki Konishi, Kei Manabe, "Palladium-Catalyzed Fluorocarbonylation Using N-Formylsaccharin as CO Source: General Access to Carboxylic Acid Derivatives"
Org. Lett. 2013, 15, 5370-5373.

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Miyuki Yamaguchi, Haruka Katsumata, Kei Manabe, "One-Pot Synthesis of Substituted Benzo[b]furans from Mono- and Dichlorophenols Using Palladium Catalysts Bearing Dihydroxyterphenylphosphine" J. Org. Chem. 2013, 78, 9270-9281.
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Tsuyoshi Ueda, Hideyuki Konishi, Kei Manabe, “Palladium-Catalyzed Reductive Carbonylation of Aryl Halides with N-Formylsaccharin as a CO Source”
Angew. Chem. Int. Ed. 2013, 52, 8611-8615.
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Kei Manabe, Takeshi Kimura, “Repetitive Synthetic Method for o,o,p-Oligophenylenes Using C−H Arylation”
Org. Lett. 2013,15, 374-377.
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Yumiko Suzuki, Mai Murofushi, Kei Manabe, “One-Pot Synthesis of Unsymmetrical Benzils and N-Heteroarenes through Nucleophilic Aroylation Catalyzed by N-Heterocyclic Carbene” Tetrahedron 2013, 69, 470.
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2012


Tsuyoshi Ueda, Hideyuki Konishi, Kei Manabe, “Trichlorophenyl Formate: Highly Reactive and Easily Accessible Crystalline CO Surrogate for Palladium-Catalyzed Carbonylation of Aryl/Alkenyl Halides and Triflates” Org. Lett. 2012,14, 5370.
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Hideyuki Konishi,
Tsuyoshi Ueda, Takashi Muto, Kei Manabe, "Remarkable Improvement Achieved by Imidazole Derivatives in Ruthenium-Catalyzed Hydroesterification of Alkenes Using Formates" Org. Lett. 2012, 14, 4722.
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Tsuyoshi Ueda, Hideyuki Konishi, Kei Manabe,
"Preparation of α,β-Unsaturated Esters and Amides via External-CO-Free Palladium-Catalyzed Carbonylation of Alkenyl Tosylates"
Tetrahedron Lett. 2012, 53, 5171-5175..
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Tsuyoshi Ueda, Hideyuki Konishi, Kei Manabe, "
Palladium-Catalyzed Carbonylation of Aryl, Alkenyl, and Allyl Halides with Phenyl Formate"
Org. Lett. 2012, 14, 3100-3103.
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2011


Ishikawa, S.; Manabe, K. "Hydroxylated Terphenylphosphine Ligands for Palladium-Catalyzed Ortho-Selective Cross-Coupling of Dibromophenols, Dibromoanilines, and Their Congeners with Grignard Reagents
" Tetrahedron 2011, 67, 10156-10163.
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Manabe, K.; Ohba, M.; Matsushima, Y. "A Repetitive One-Step Method for Oligoarene Synthesis Using Catalyst-Controlled Chemoselective Cross-Coupling" Org. Lett. 2011, 13, 2436-2439.


2010


Wang, J.-R.; Manabe, K. “Hydroxyterphenylphoshine-Palladium Catalyst for Benzo[b]furan Synthesis from 2-Chlorophenols. Bifunctional Ligand Strategy for Cross-Coupling of Chloroarenes” J. Org. Chem. 2010, 75, 5340-5342.
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Konishi, H.; Itoh, T.; Manabe, K. “Site-Selective Cross-Coupling of Dichlorinated Benzo-Fused Nitrogen-Heterocycles with Grignard Reagents” Chem. Pharm. Bull. 2010, 58, 1255-1258.
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Ishikawa, S.; Manabe, K. “DHTP Ligands for the Highly Ortho-Selective, Palladium-Catalyzed Cross-Coupling with Grignard Reagents: A Conformational Approach for Catalyst ImprovementAngew. Chem. Int. Ed. 2010, 49, 772-775.
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Ishikawa, S.; Manabe, K. “Synthesis of Hydroxylated Oligoarene-Type Phosphines by a Repetitive Two-Step Method” Tetrahedron 2010, 66, 297-303.
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